Valence electrons: definition in chemistry

Valence electrons: The electrons in the outermost shell of an atom; they are the ones that take part in chemical bonding.

The number of valence electrons largely decides how an element reacts, because atoms tend to gain, lose or share electrons to reach a stable arrangement, often eight outer electrons (the octet rule). Lewis dot structures show valence electrons as dots around the element symbol. For transition metals the picture is more complicated, because electrons in the inner d sublevel can also take part in bonding.

Examples

On the periodic table

For main-group elements the group tells you the number of valence electrons: groups 1 and 2 have 1 and 2, and groups 13 to 18 have 3 to 8 (helium has 2).

Related terms

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